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131391-55-4 - Magnesium monoperoxyphthalate hexahydrate, tech. ca 80% - Monoperoxyphthalic acid magnesium salt hexahydrate - Magnesium bis(monoperoxyphthalate) hexahydrate - B20565 - Alfa Aesar

B20565 Magnesium monoperoxyphthalate hexahydrate, tech. ca 80%

Numéro CAS
131391-55-4
Synonymes
Monoperoxyphthalic acid magnesium salt hexahydrate
Magnesium bis(monoperoxyphthalate) hexahydrate

Dimensions Prix ($) Quantité Disponibilité
25g 24,40
250g 116,00
1000g 332,00
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Magnesium monoperoxyphthalate hexahydrate, tech. ca 80%

MDL
MFCD00013096
EINECS
279-013-0

Propriétés chimiques

Formule
C16H10MgO10•6H2O
Poids formulaire
494.65 (386.55anhy)
Point de fusion
ca 93° dec.
Solubilité
Soluble in water

Références bibliographiques

Alternative reagent with enhanced stability for many of the reactions conventionally carried out using 3-Chloroperoxybenzoic acid, L00286. For a comparative study of the two reagents, see: Synthesis, 1015 (1987).

/n

For regioselective epoxidation of allylic alcohols in water, see: J. Org. Chem., 57, 1198 (1992).

/n

Cyclic ketones undergo the Baeyer-Villiger reaction to give lactones in high yield, in acetonitrile: Synth. Commun., 26, 4591 (1996), or in methanol-water in the presence of NaHCO3: J. Org. Chem., 62, 2633 (1997); the latter method has been used in the synthesis of massoia lactone.

/n

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,5673
Code tarifaire harmonisé
2917.39
TSCA
No

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