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2926-30-9 - Sodium trifluoromethanesulfonate, 98% - Sodium triflate - Trifluoromethanesulfonic acid sodium salt - B20776 - Alfa Aesar

B20776 Sodium trifluoromethanesulfonate, 98%

Numéro CAS
2926-30-9
Synonymes
Sodium triflate
Trifluoromethanesulfonic acid sodium salt

Dimensions Prix ($) Quantité Disponibilité
5g 37,08
25g 123,98
100g 376,20
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Sodium trifluoromethanesulfonate, 98%

MDL
MFCD00061607

Propriétés chimiques

Formule
CF3SO3Na
Poids formulaire
172.06
Point de fusion
251-255°
Sensibilité
Hygroscopic
Solubilité
Soluble in water.

Applications

Sodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).

Notes

Hygroscopic. Incompatible with strong oxidizing agents, acids and bases.

Références bibliographiques

Sulfinylation of aromatic compounds can be brought about in triflic acid at room temperature to give good yields of aryl trifluoromethyl sulfoxides: Synlett, 550 (2001).

Catalyzes the aza Diels-Alder reaction of Danishefsky's diene (1-Methoxy-3-trimethyl­siloxy-1,3-butadiene, L14672) with imines in water under neutral conditions: Chem. Commun., 574 (2003).

Lima, F. S.; Cuccovia, I. M.; Buchner, R.; Antunes, F. E.; Lindman, B.; Miguel, M. G.; Horinek, D.; Chaimovich, H. Sodium Triflate Decreases Interaggregate Repulsion and Induces Phase Separation in Cationic Micelles. Langmuir 2015, 31 (9), 2609-2614.

Ji, X. M.; Wei, L.; Chen, F.; Tang, R. Y. Direct trifluoromethylation of imidazoheterocycles in a recyclable medium at room temperature. RSC Adv. 2015, 5 (38), 29766-29773.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
3728797
Code tarifaire harmonisé
2904.10
TSCA
No

Recommandé

  • A10173

    Trifluoromethanesulfonic acid, 98+%
  • A10232

    trans-Stilbene, 98%
  • A10329

    Magnesium nitrate hexahydrate, 98%
  • A12393

    Sodium tetrafluoroborate, 97%
  • 11623

    Sodium perchlorate, anhydrous, ACS, 98.0-102.0%

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