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823-76-7 - Cyclohexyl methyl ketone, 95% - Acetylcyclohexane - Hexahydroacetophenone - B21000 - Alfa Aesar

B21000 Cyclohexyl methyl ketone, 95%

Numéro CAS
823-76-7
Synonymes
Acetylcyclohexane
Hexahydroacetophenone

Dimensions Prix ($) Quantité Disponibilité
5g 33,00
25g 101,00
100g 335,00
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Cyclohexyl methyl ketone, 95%

MDL
MFCD00040418
EINECS
212-517-0

Propriétés chimiques

Formule
C8H14O
Poids formulaire
126.20
Point de fusion
-34°
Point d'ébullition
181-183°
Point d'éclair
66°(151°F)
Densité
0.917
Indice de réfraction
1.4520
Solubilité
Not miscible or difficult to mix in water.

Applications

It can be used to produce acetoxycyclohexane. It is also used as a pharmaceutical intermediate.

Notes

Store away from oxidizing agents and bases. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Références bibliographiques

Bach RD. The role of acid catalysis in the Baeyer-Villiger reaction. A theoretical study.J Org Chem.201277(16), 6801-15.

Thomas M. Bare and Herbert O. House. Methyl Ketones from Carboxylic Acids: Cyclohexyl Methyl Ketone.Org. Synth.

Monobromination of unsymmetrical ketones at the less-substituted carbon atom in methanol gives results which parallel the bromination of the corresponding acetal, and in this case results in exclusive reaction at the methyl group: Org. Synth. Coll., 6, 193 (1988).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Mentions de prudence: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
507229
Code tarifaire harmonisé
2914.29
TSCA
No
RTECS
KM5638850

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Analytique et matériel de laboratoire