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12150-46-8 - 1,1'-Bis(diphenylphosphino)ferrocene, 97% - Dppf - 1,1'-Ferrocenebis(diphenylphosphine) - B21166 - Alfa Aesar

B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97%

Numéro CAS
12150-46-8
Synonymes
Dppf
1,1'-Ferrocenebis(diphenylphosphine)

Dimensions Prix ($) Quantité Disponibilité
1g 34,10
5g 96,60
25g 433,00
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1,1'-Bis(diphenylphosphino)ferrocene, 97%

MDL
MFCD00001422
EINECS
430-420-3

Propriétés chimiques

Formule
C34H28FeP2
Poids formulaire
554.40
Point de fusion
ca 182° dec.
Sensibilité
Air Sensitive
Solubilité
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Applications

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Notes

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Références bibliographiques

Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).

Li, C. G.; Xue, F.; Cui, M. J.; Shang, J. Y.; Lou, T. J. 1,1'-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons. Transition Met. Chem. 2015, 40 (1), 47-52.

Kaur-Ghumaan, S.; Sreenithya, A.; Sunoj, R. B. Synthesis, characterization and DFT studies of 1, 1'-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes. J. Chem. Sci. 2015, 127 (3), 557-563.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé
2931.90
TSCA
No

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