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122-79-2 - Phenyl acetate, 99% - Acetic acid phenyl ester - B22561 - Alfa Aesar

B22561 Phenyl acetate, 99%

Numéro CAS
122-79-2
Synonymes
Acetic acid phenyl ester

Dimensions Prix ($) Quantité Disponibilité
250g 32,96
1000g 104,03
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Phenyl acetate, 99%

MDL
MFCD00008699
EINECS
204-575-0

Propriétés chimiques

Formule
CH3CO2C6H5
Poids formulaire
136.15
Point d'ébullition
195-196°
Point d'éclair
76°(168°F)
Densité
1.075
Indice de réfraction
1.5020
Solubilité
Soluble in water (4 g/L at 20°C).

Applications

Phenyl acetate levels in urine are marker for the diagnosis of some forms of unipolar major depressive disorders. It undergoes Fries rearrangement to form a mixture of o- and p-hydroxyacetophenones which are useful intermediates in manufacture of pharmaceuticals. It is a metabolite of Phenylbutyrate (PB), useful in the treatment of neuroblastoma and lung cancer. An odorant found in strawberries, passion fruit and black tea.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Références bibliographiques

H.C.Sabelli; J.Fawcett; F.Gusovsky; J.Javaid; J.Edwards; H.Jeffriess. Urinary phenyl acetate: a diagnostic test for depression? Science. 1983, 220,(4602), 1187-1188.

 

F.Jayat; M.J.Sabater Picot; M.Guisnet. Solvent effects in liquid phase Fries rearrangement of phenyl acetate over a HBEA zeolite. Catalysis Letters. 1996, 41,(3), 181-187.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H302-H227

Harmful if swallowed. Combustible liquid.

Mentions de prudence: P210-P280-P264-P270-P301+P312-P330-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,7267
Beilstein
636458
Code tarifaire harmonisé
2915.39
TSCA
Yes
RTECS
AJ2800000

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Consulté récemment

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Catalyseurs

Analytique et matériel de laboratoire