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7400-27-3 - tert-Butylhydrazine hydrochloride, 98% - B23876 - Alfa Aesar

B23876 tert-Butylhydrazine hydrochloride, 98%

Numéro CAS
7400-27-3
Synonymes

Dimensions Prix ($) Quantité Disponibilité
25g 26,01
100g 62,98
500g 177,84
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tert-Butylhydrazine hydrochloride, 98%

MDL
MFCD00012947
EINECS
231-001-6

Propriétés chimiques

Formule
(CH3)3CNHNH2•HCl
Poids formulaire
124.61
Point de fusion
ca 192° dec.
Sensibilité
Hygroscopic
Solubilité
Solubility in water (almost transparency). Soluble in DMSO and methanol.

Applications

It is used in organic synthesis for aromatic nucleophilic N-N exchange reaction. tert-Butylhydrazine Hydrochloride is also used in the preparation of insect growth regulator. tert-Butylhydrazine hydrochloride was used in the synthesis of diphosphinohydrazines, 5-amino-1-tert-butyl-3-(p-chlorophenyl)-4-cyanopyrazole and 1,3,4,5-tetrasubstituted pyrazole derivatives.

Notes

Hygroscopic. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Protect from humidity and water.

Références bibliographiques

Clarissa P. Frizzo, et al. Ionic liquid effects on the reaction of β-enaminones and tert-butylhydrazine and applications for the synthesis of pyrazoles.Catal. Commun..,2009,10(15), 1967-1970.

Yoshihiro Sawada, et al. Synthesis and insecticidal activity of benzoheterocyclic analogues of N?-benzoyl-N-(tert-butyl)benzohydrazide: Part 3. Modification of N-tert-butylhydrazine moiety.Pest Management Science.,2003,59(1), 49-57.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
3651224
Code tarifaire harmonisé
2928.00
TSCA
Yes
RTECS
MV2841000

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Analytique et matériel de laboratoire