Consentement d'utilisation des Cookies

J'accepte Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

623-71-2 - Ethyl 3-chloropropionate, 98% - 3-Chloropropionic acid ethyl ester - B23907 - Alfa Aesar

B23907 Ethyl 3-chloropropionate, 98%

Numéro CAS
623-71-2
Synonymes
3-Chloropropionic acid ethyl ester

Dimensions Prix ($) Quantité Disponibilité
25g 32,60
100g 92,30
250g 166,00
Ajouter au panier Ajouter au devis en vrac Afficher l'article

Ethyl 3-chloropropionate, 98%

MDL
MFCD00000989
EINECS
210-809-2

Propriétés chimiques

Formule
ClCH2CH2CO2CH2CH3
Poids formulaire
136.58
Point d'ébullition
162-164°
Point d'éclair
61°(142°F)
Densité
1.101
Indice de réfraction
1.4250
Solubilité
Immiscible in water.

Applications

It can be used to produce (1-ethoxycyclopropyloxy)trimethylsilane by heating.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Références bibliographiques

O. L. Epstein, et al. On the mechanism of titanium-catalyzed cyclopropanation of esters with aliphatic organomagnesium compounds. Deuterium distribution in the reaction products of (CD3)2CHMgBr with ethyl 3-chloropropionate in the presence of titanium tetraisopropoxide.Russ. Chem. Bull.,2000,49(2), 378-380.

Herbert C. Brown, et al. Improved procedure for the asymmetric reduction of prochiral ketones by B-3-pinanyl-9-borabicyclo[3.3.1]nonane.J. Org. Chem.,1982,47(8), 1606-1608.

Reductive cyclization with Na metal in the presence of TMS chloride gives a cyclopropanone acetal, which has been used as a precursor of 1-lithio-1-ethoxycyclopropane: Tetrahedron Lett., 25, 5851 (1984); Org. Synth. Coll., 7, 131 (1990):

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Mentions de prudence: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
385698
Code tarifaire harmonisé
2915.90
TSCA
Yes

Recommandé

  • A10199

    L-Proline, 99%
  • A11437

    Dimethyl acetylenedicarboxylate, 98%
  • A12788

    Iodobenzene, 98%
  • A14687

    1,3-Dibromopropane, 98%
  • 41675

    Ethylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire