B23998 3-Bromopropionitrile, 98%
FDS
| Conditionnement | Prix ($) | Quantité | Disponibilité |
|---|---|---|---|
| 25g | 22,20 |
|
|
| 100g | 79,60 |
|
|
3-Bromopropionitrile, 98%
Propriétés chimiques
Applications
3-Bromopropionitrile was used as the initiator in the atom transfer radical polymerization of acrylonitrile. It was used in coupling reactions of a number of aromatic and heteroaromatic phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite.
Notes
Références bibliographiques
Dora Demeter; Philippe Blanchard; Ion Grosu; Jean Roncali. Electropolymerization of crown-annelated bithiophenes. Electrochemistry Communications. 2007, 9 (7), 1587-1591.
Edward S. Binkley; Clayton H. Heathcock. Regiospecific alkylation of enolate ions in liquid ammonia-tetrahydrofuran. J. Org. Chem. 1975, 40 (15), 2156-2160.
Reagent for protection of thiols (K 2 CO 3 - DMF) as S-2-cyanoethyl thioethers. Deprotection can be effected with conc. ammonia: Nucleic Acids Res., 19, 5719 (1991), K 2 CO 3 /NaBH 4 in DMF: Tetrahedron Lett., 27, 203 (1986), or KO-t-Bu - DMF: Bull. Chem. Soc. Jpn., 63, 829 (1990).
Mentions de danger et de prudence du SGH
Mentions de danger (UE): H300-H310-H330-H315-H319-H335
Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Mentions de prudence: P260-P201-P280g-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.
