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142421-57-6 - Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals - Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine - H25883 - Alfa Aesar

H25883 Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

Numéro CAS
142421-57-6
Synonymes
Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine

Dimensions Prix ($) Quantité Disponibilité
1g 81,58
5g 243,08
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Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

MDL
MFCD01630852
EINECS
000-000-0

Propriétés chimiques

Formule
C16H6ClF12P
Poids formulaire
492.63
Sensibilité
Air & Moisture Sensitive
Solubilité
Reacts with water.

Applications

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Notes

Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

Références bibliographiques

Hong Jin; Da-yu Wang; Yi-fang Mei; Wen-bing Qiu; Yi Zhou; Dong-ming Wang; Xue-rui Tan; Yu-guang Li. Mitogen-activated protein kinases pathway is involved in physiological testosterone-induced tissue factor pathway inhibitor expression in endothelial cells. Blood Coagulation and Fibrinolysis. 2010, 21 (5), 420-424.

R. Oost; J. Rong; A. J. Minnaard and S. R. Harutyunyan. Synthesis of new derivatives of copper complexes of Josiphos family ligands for applications in asymmetric catalysis. Catal. Sci. Technol. 2014, 4 (7), 1997-2005.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
No

Recommandé

  • A10199

    L-Proline, 99%
  • H25885

    Chlorobis(3,5-dimethylphenyl)phosphine, tech. 90%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%

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