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59831-02-6 - Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II) - [1,3-Bis(diphenylphosphino)propane]dichloropalladium(II) - H26897 - Alfa Aesar

H26897 Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

Numéro CAS
59831-02-6
Synonymes
[1,3-Bis(diphenylphosphino)propane]dichloropalladium(II)

Dimensions Prix ($) Quantité Disponibilité
250mg 90,00
1g 225,00
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Dichloro[bis(1,3-diphenylphosphino)propane]palladium(II)

MDL
MFCD03844773

Propriétés chimiques

Formule
C27H26Cl2P2Pd
Poids formulaire
589.77
Sensibilité
Air Sensitive
Solubilité
Soluble in dichloromethane.

Applications

(1,3-Bis(diphenylphosphino)propane)palladium(II) chloride, used ubiquitously as a employed preparation of palladium for cross-coupling protocols in organic synthesis. It is also a useful organo-metallic chemical catalyst. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in coupling reactions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents. Air Sensitive.

Références bibliographiques

CS Shultz.; J Ledford.; JM DeSimone. Kinetic Studies of Migratory Insertion Reactions at the (1,3-Bis(diphenylphosphino)propane)Pd(II) Center and Their Relationship to the Alternating Copolymerization of Ethylene and Carbon Monoxide. J. Am. Chem. Soc. 2000122 (27), 6351-6356.

M Sundermeier.; A Zapf.; M Beller.; J Sans. A new palladium catalyst system for the cyanation of aryl chlorides. Tetrahedron Letters. 200142 (38), 6707-6710.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé
2843.90
TSCA
No

Recommandé

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