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128388-54-5 - 1,1':3',1''-Terphenyl-5'-boronic acid, 95% - 3,5-Diphenylbenzeneboronic acid - (3,5-Diphenylphenyl)boronic acid - H27640 - Alfa Aesar

H27640 1,1':3',1''-Terphenyl-5'-boronic acid, 95%

Numéro CAS
128388-54-5
Synonymes
3,5-Diphenylbenzeneboronic acid
(3,5-Diphenylphenyl)boronic acid

Dimensions Prix ($) Quantité Disponibilité
250mg 45,92
1g 144,20
5g 437,75
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1,1':3',1''-Terphenyl-5'-boronic acid, 95%

MDL
MFCD09953491

Propriétés chimiques

Formule
C18H15BO2
Poids formulaire
274.13
Point de fusion
292-296°
Solubilité
Insoluble in water.

Applications

A double Suzuki cross-coupling protocol has been devised as a practical route to a variety of terphenyls. Good chemoselectivity was observed. Unsymmetrically substituted triphenylenes were also easily prepared. A double Suzuki cross-coupling protocol has been devised as a practical route to a variety of terphenyls and triphenylenes.

Notes

Refrigerated (2-4°C). Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Références bibliographiques

M.J. Sharp,; W. Cheng,; V. Snieckus. Synthetic connections to the aromatic directed metalation reaction. Functionalized aryl boronic acids by ipso borodesilylation. General syntheses of unsymmetrical biphenyls and m-terphenyls. Tetrahedron Letters. 1987, 28 (43),5093-5096.

Daniele Simonia,; Giuseppe Gianninib,; Pier Giovanni Baraldia,; Romeo Romagnolia,; Marinella Robertic,; Riccardo Rondanina,; Riccardo Baruchelloa,; Giuseppina Grisoliaa,; Marcello Rossia,; Danilo Mirizzia,; Francesco Paolo Invidiatad,; Stefania Grimaudoe,; Manlio Tolomeo. A convenient synthesis of unsymmetrically substituted terphenyls of biologically active stilbenes via a double Suzuki cross-coupling protocol. Tetrahedron Letters. 2003, 44 (14), 3005-3008.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé
2931.90
TSCA
No

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Catalyseurs

Analytique et matériel de laboratoire