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33527-91-2 - Tris(2-dimethylaminoethyl)amine, 99+% - Me6TREN - H31853 - Alfa Aesar

H31853 Tris(2-dimethylaminoethyl)amine, 99+%

Numéro CAS
33527-91-2
Synonymes
Me6TREN

Dimensions Prix ($) Quantité Disponibilité
5g 118,45
25g 393,46
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Tris(2-dimethylaminoethyl)amine, 99+%

MDL
MFCD00015607

Propriétés chimiques

Formule
C12H30N4
Poids formulaire
230.40
Point d'ébullition
70-71°/0.5mm
Indice de réfraction
1.4540
Sensibilité
Air Sensitive & Hygroscopic
Solubilité
Miscible with water.

Applications

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Notes

Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Références bibliographiques

Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.

Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2921.29
TSCA
Yes

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Consulté récemment

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Catalyseurs

Analytique et matériel de laboratoire