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122-56-5 - Tri-n-butylborane, 1M soln. in THF - H32518 - Alfa Aesar

H32518 Tri-n-butylborane, 1M soln. in THF

Numéro CAS
122-56-5
Synonymes

Dimensions Prix ($) Quantité Disponibilité
100ml 178,00
500ml 490,00
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Tri-n-butylborane, 1M soln. in THF

MDL
MFCD00009423

Propriétés chimiques

Formule
C12H27B
Poids formulaire
182.16
Densité
0.834
Solubilité
Not miscible or difficult to mix with water.

Applications

Tri-n-butylborane is used as a reactant for addition reactions for synthesis of phenyltrialkylborate salts, boron-based multicomponent reactions for generation of substituted aziridines, oxazolidines, and pyrrolidines, Suzuki-Miyaura cross coupling of halopurines with trialkylboranes for the synthesis of adenosine A2A receptor antagonists, multicomponent C-alkylation reactions with aromatic aldimines, one-pot alkylation-boration and electrophilic substitution.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Références bibliographiques

Masuhiro Tsukada.; Takashi Yamamoto.; Nobuo Nakabayashi.; Hiroshi Ishikawa.; Giuliano Freddi. Grafting of methyl methacrylate onto silk fibers initiated by tri-n-butylborane. Journal of Applied Polymer Science. 1991, 43 (11), 2115-2121.

Hideo Matsumura.; Takuo Tanaka.; Yohsuke Taira.; Mitsuru Atsuta. Bonding of a cobalt-chromium alloy with acidic primers and tri-n-butylborane-initiated luting agents. The Journal of Prosthetic Dentistry. 1996, 76 (2), 194-199.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H351-H302-H319-H335

Highly flammable liquid and vapour. Suspected of causing cancer. Harmful if swallowed. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P201-P261-P280-P281-P303+P361+P353-P305+P351+P338-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
Yes

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