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10294-34-5 - Boron trichloride, 1M soln. in hexanes, mixed isomers - H32833 - Alfa Aesar

H32833 Boron trichloride, 1M soln. in hexanes, mixed isomers

Numéro CAS
10294-34-5
Synonymes

Dimensions Prix ($) Quantité Disponibilité
100ml 63,36
500ml 211,50
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Boron trichloride, 1M soln. in hexanes, mixed isomers

MDL
MFCD00011313
EINECS
233-658-4

Propriétés chimiques

Formule
BCl3
Poids formulaire
117.17
Densité
0.738
Sensibilité
Moisture Sensitive
Solubilité
Reacts with water.

Applications

A mild, selective combination reagent for the cleavage of primary alkyl aryl ethers. Boron trichloride is a selective demethylating agent. For preparing methyl esters of fatty acids and for transesterification of triglycerides. Mainly used as semiconductor silicon doping source or organic synthesis catalyst, also used for making high purity boron or organic boron.

Notes

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture, heat. Unstable. Store at 2-8°C.

Références bibliographiques

F.M. Dean,; J.Goodchild,; L.E. Houghton,; J.A. Martin,; R.B. Morton,; B. Parton,; A.W. Price, ;Nongyow Somvichien. Boron trichloride as a selective demethylating agent. Tetrahedron Letters. 1996, 7(35),4153-4159.

N. N. Greenwood,; K. Wade .Complexes of boron trichloride with pyridine and piperidine. J. Chem. Soc., year of publication , 1130-1141.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H300-H331-H336-H304-H361-H373-H314-H411

Highly flammable liquid and vapour. Fatal if swallowed. Toxic if inhaled. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage. Toxic to aquatic life with long lasting effects.

Mentions de prudence: P210-P260-P201-P261-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2812.10
TSCA
Yes

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