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89719-92-6 - 2,5-Dichloro-4-(trifluoromethyl)pyridine, 97% - H33442 - Alfa Aesar

H33442 2,5-Dichloro-4-(trifluoromethyl)pyridine, 97%

Numéro CAS
89719-92-6
Synonymes

Dimensions Prix ($) Quantité Disponibilité
250mg 63,04
1g 197,10
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2,5-Dichloro-4-(trifluoromethyl)pyridine, 97%

MDL
MFCD09749663

Propriétés chimiques

Formule
C6H2Cl2F3N
Poids formulaire
215.99
Point d'ébullition
76°/18mm

Applications

2-chloro-6-(trifluoromethyl)pyridine, 2-chloro-5-(trifluoromethyl)pyridine and 3-chloro-4-(trifluoromethyl)pyridine were each converted into the three possible carboxylic acids 2, 4, 6,8, 10, 12, 16, 17 and 20. This was achieved by employing several, but not all of the organometallic “toolbox methods”: transformation of a more basic organometallic species into a less basic isomer by transmetalation-equilibration.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, aluminum. Protection under nitrogen and lower temperature is recommended(below 4 deg C).

Références bibliographiques

Florence Mongin,; Antonio Tognini,; Fabrice Cottet,; Manfred Schlosses. Halogen shuffling in pyridines: Site selective electrophilic substitutions of 2-chloro-6-(trifluoromethyl)pyridine. Tetrahedron Letters. 1998, 39(13), 1749-1752.

Fabrice Cottet,; Marc Marull,; Olivier Lefebvre,; Manfred Schlosser. Recommendable Routes to Trifluoromethyl-Substituted Pyridine- and Quinolinecarboxylic Acids. European Journal of Organic Chemistry. 2003, 81559-1568,.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H301-H315-H319-H335-H226

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Flammable liquid and vapour.

Mentions de prudence: P210-P261-P280-P301+P310-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
3
Groupe d'emballage
III
Code tarifaire harmonisé
2933.39
TSCA
No

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