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2234-82-4 - n-Propylmagnesium chloride, 1M in MeTHF - H51162 - Alfa Aesar

H51162 n-Propylmagnesium chloride, 1M in MeTHF

Numéro CAS
2234-82-4
Synonymes

Dimensions Prix ($) Quantité Disponibilité
100ml 42,90
500ml 161,00
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n-Propylmagnesium chloride, 1M in MeTHF

MDL
MFCD00000474

Propriétés chimiques

Formule
CH3CH2CH2MgCl
Poids formulaire
102.85
Sensibilité
Air & Moisture Sensitive
Solubilité
Reacts with water.

Applications

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF). Also used as reactant in Grignard-reactions for the introduction of the n-propyl group.

Notes

Air and Moisture Sensitive, store away from air and water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

Kenneth N. Campbell; James O. Knobloch; Barbara K. Campbell. The Preparation and Some Reactions of 1,1,1-Trifluoro-2-alkenes.J. Am. Chem. Soc.,1950, 72(10), 4380-4384.

Rima S. Al-awar; Sajan P. Joseph; Daniel L. Comins. Conversion of N-acyl-2,3-dihydro-4-pyridones to 4-chloro-1,2-dihydropyridines using the Vilsmeier Reagent. Synthesis of (-)-coniine and (±)-lupinine. J. Org. Chem., 1993, 58(27), 7732-7739.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H261-H314

Highly flammable liquid and vapour. In contact with water releases flammable gas. Causes severe skin burns and eye damage.

Mentions de prudence: P210-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
4.3
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
Yes

Recommandé

  • A10559

    Iodomethane, 99%, stab. with copper
  • H27078

    (S)-(+)-1-Bromo-2-methylbutane, 97%, stab. with potassium carbonate
  • 33337

    Magnesium sulfate, anhydrous, 99.5% min

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire