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6783-05-7 - trans-beta-Styrylboronic acid, 97% - trans-Phenylethenylboronic acid - trans-2-Phenylvinylboronic acid - H53227 - Alfa Aesar

H53227 trans-beta-Styrylboronic acid, 97%

Numéro CAS
6783-05-7
Synonymes
trans-Phenylethenylboronic acid
trans-2-Phenylvinylboronic acid

Dimensions Prix ($) Quantité Disponibilité
1g 35,10
5g 140,00
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trans-beta-Styrylboronic acid, 97%

MDL
MFCD00963621

Propriétés chimiques

Formule
C8H9BO2
Poids formulaire
147.97
Point de fusion
98-100°

Applications

trans-beta-Styrylboronic acid as reagent is used for palladium (Pd)-catalyzed Suzuki-Miyaura coupling reactions, diastereoselective synthesis via Pd-catalyzed Heck-Suzuki cascade reaction and rhodium (Rh)-catalyzed intramolecular amination of aryl azides. It is also used as reagent in preparation of optically active unsaturated amino acids by diastereoselective Petasis borono-Mannich reaction and amino alcohol dienes via Petasis 3-component reaction using Ru-catalyzed ring-closing metathesis and isomerization.

Notes

Stable under recommended storage conditions. Incompatible with oxidizing agents and heat.

Références bibliographiques

Yi Li; Ming-Hua Xu. Lewis acid promoted highly diastereoselective Petasis Borono-Mannich reaction: efficient synthesis of optically active β,γ-unsaturated α-amino acids. Organic Letters. 2012, 14, (8),2062-2065

 

Erhad Ascic; Sebastian T.Le Quement; Mette Ishoey; Mathilde Daugaard; Thomas E.Nielsen. Build/couple/pair strategy combining the Petasis 3-component reaction with Ru-catalyzed ring-closing metathesis and isomerization. ACS Combinatorial Science. 2012, 14, (4),253-257

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé
2931.90
TSCA
No

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Consulté récemment

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Analytique et matériel de laboratoire