4-(Dimethylamino)phenylboronic acid is a useful reagent for Suzuki-Miyaura cross-coupling reactions, Rhodium (Rh)-catalyzed asymmetric addition reactions, Palladium (Pd)-catalyzed C-OH bond activation. This reagent is used in Preparation of Push-pull arylvinyldiazine chromophores, Helical ortho-phenylene oligomers with terminal push-pull substitution, Alginate-supported cation-Pd nanoparticle gels as catalysts for the Suzuki-Miyaura cross-coupling reaction, Organic dyes for dye-sensitized solar cells.
Catherine J. Aspley.; J. A. Gareth Williams. Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality. New J. Chem. 25, (9), 1136-1147.
Wendy Goodall.; J. A. Gareth Williams. A new, highly fluorescent terpyridine which responds to zinc ions with a large red-shift in emission. Chem. Commun. 2001, (23),2514-2515.
Mentions de danger (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Mentions de prudence: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant