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312624-26-3 - 2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58695 - Alfa Aesar

H58695 2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Numéro CAS
312624-26-3
Synonymes

Dimensions Prix ($) Quantité Disponibilité
50ml 168,92
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2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671974

Propriétés chimiques

Formule
C3H4BrNZn
Poids formulaire
199.36
Densité
0.955
Sensibilité
Air Sensitive
Solubilité
Reacts with water.

Applications

It is employed as a intermediate for pharmaceutical. Also used as efficient cyanide ion source for palladium-catalyst.

Notes

Air Sensitive, store away from air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

Toshikatsu Takanami; Mikiko Hayashi; Hiroshi Chijimatsu; Wakaba Inoue; and Kohji Suda. Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide as an Efficient Cyanide Ion Source. Org. Lett.,2005, 7(18), 3937-3940.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H261-H300-H335-H314-H351

Highly flammable liquid and vapour. In contact with water releases flammable gas. Fatal if swallowed. May cause respiratory irritation. Causes severe skin burns and eye damage. Suspected of causing cancer.

Mentions de prudence: P210-P231+P232-P260-P201-P261-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
4.3
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
No

Recommandé

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    6-Chlorohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58397

    2-Thienylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58408

    1-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

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