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171860-68-7 - Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles - H58764 - Alfa Aesar

H58764 Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Numéro CAS
171860-68-7
Synonymes

Dimensions Prix ($) Quantité Disponibilité
50ml 201,00
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Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00671991

Propriétés chimiques

Formule
C5H9BrZn
Poids formulaire
214.41
Densité
0.955
Sensibilité
Air Sensitive
Solubilité
Reacts with water.

Applications

It is an active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.

Notes

Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents, heat, acids and water.

Références bibliographiques

Keith Biggadike.; Mohamed Boudjelal.; Margaret Clackers.; Diane M. Coe.; Derek A. Demaine.; George W. Hardy.; Davina Humphreys.; Graham G. A. Inglis.; Michael J. Johnston.; Haydn T. Jones.; David House.; Richard Loiseau.; Deborah Needham.; Philip A. Skone, Iain Uings.; Gemma Veitch.; Gordon G. Weingarten.; Iain M. McLay.; Simon J. F. Macdonald. Nonsteroidal Glucocorticoid Agonists: Tetrahydronaphthalenes with Alternative Steroidal A-Ring Mimetics Possessing Dissociated (Transrepression/Transactivation) Efficacy Selectivity. J. Med. Chem. 2007, 50 (26),6519-6534.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H261-H302-H333-H314-H318-H351-H335

Highly flammable liquid and vapour. In contact with water releases flammable gas. Harmful if swallowed. May be harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer. May cause respiratory irritation.

Mentions de prudence: P223-P210-P231+P232-P260u-P201-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Obtain special instructions before use. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
4.3
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
No

Recommandé

  • H58852

    Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58595

    2-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58695

    2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • H58962

    3-Cyanopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

Consulté récemment

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Catalyseurs

Analytique et matériel de laboratoire