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333-27-7 - Methyl trifluoromethanesulfonate, 97% - Trifluoromethanesulfonic acid methyl ester - H61758 - Alfa Aesar

H61758 Methyl trifluoromethanesulfonate, 97%

Numéro CAS
333-27-7
Synonymes
Trifluoromethanesulfonic acid methyl ester

Dimensions Prix ($) Quantité Disponibilité
25g 108,15
100g 336,81
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Methyl trifluoromethanesulfonate, 97%

MDL
MFCD00000409
EINECS
206-371-7

Propriétés chimiques

Formule
C2H3F3O3S
Poids formulaire
164.10
Point d'ébullition
99°
Point d'éclair
38°(100°F)
Densité
1.500
Indice de réfraction
1.3260
Sensibilité
Air Sensitive

Applications

Methyl trifluoromethanesulfonate is used as a powerful methylating reagent in chemistry. Further, it is used in the conversion of amines to methyl ammonium triflates. In addition, it is also used in Suzuki reaction.

Notes

Air and moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents, strong bases, strong acids and strong reducing agents. Hydrolyzes with water.

Références bibliographiques

Huang, X.; Gillies, R. J.; Tian, H. Synthesis of [18F] 4-amino-N-(3-chloro-4-fluorophenyl)-N'-hydroxy-1, 2, 5-oxadiazole-3-carboximidamide (IDO5L): a novel potential PET probe for imaging of IDO1 expression. J. Labelled Compd. Radiopharm. 2015, 58 (4), 156-162.

Phelan, V. V.; Moree, W. J.; Aguilar, J.; Cornett, D. S.; Koumoutsi, A.; Noble, S. M.; Pogliano, K.; Guerrero, C. A.; Dorrestein, P. C. Impact of a transposon insertion in phzF2 on the specialized metabolite production and interkingdom interactions of Pseudomonas aeruginosa. J. Bacteriol. 2014, 196 (9), 1683-1693.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318-H226

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour.

Mentions de prudence: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2905.19
TSCA
Yes

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Analytique et matériel de laboratoire