Consentement d'utilisation des Cookies

J'accepte. Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

H63502 (S)-(-)-Glycidol, 99+%, ee 99+%

Numéro de CAS
60456-23-7
Synonymes
(S)-(-)-Oxirane-2-methanol
(S)-(-)-2,3-Epoxy-1-propanol

Stock No. Conditionnement Prix ($) Quantité Disponibilité
H63502-03 1g 24,80
H63502-06 5g 88,10
H63502-14 25g 315,00
Ajouter au panier Ajouter au devis en vrac Afficher l'article

(S)-(-)-Glycidol, 99+%, ee 99+%

MDL
MFCD00074874

Propriétés chimiques

Formule
C3H6O2
Poids moleculaire
74.08
Point d'ébullition
66-67°/19mm
Point d'éclair
66°(151°F)
Densité
1.116
Indice de réfraction
1.4330
Storage & Sensitivity
Store at -20°C.
Solubilité
Soluble in chloroform, DMSO and methanol.

Applications

(S)-(-)-Glycidol is employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis. Also used as a starting reagent to synthesize non-peptidic HIV protease inhibitors.

Notes

Store in freezer at(-20°C). Keep container tightly closed. Store away from oxidizing agent.

Références bibliographiques

Neil A Sheddan; Johann Mulzer. Cross metathesis as a general strategy for the synthesis of prostacyclin and prostaglandin analogues. Organic Letters. 2006, 8(14), 3101-3104.

Haines TD; Adlaf KJ; Pierceall RM, et al. Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC-TOFMS. J. Am. Oil Chem. Soc. 2011, 88(1), 1-14.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H227-H302-H312-H315-H319-H331-H335-H340-H350-H360

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. May cause respiratory irritation. May cause genetic defects. May cause cancer. May damage fertility or the unborn child.

Mentions de prudence: P201-P202-P210-P235-P261-P264b-P270-P271-P280i-P281-P301+P312-P302+P352-P304+P340-P305+P351+P338-P308+P313-P311-P312-P330-P332+P313-P337+P313-P362-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Autres références

Beilstein
79783
Classe de danger
6.1
Groupe d'emballage
III
Code tarifaire harmonisé
2910.90
TSCA
No
RTECS
RR0508100

Recommandé

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire