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89878-14-8 - Diethyl(3-pyridyl)borane, 98% - 3-(Diethylboryl)pyridine - H64225 - Alfa Aesar

H64225 Diethyl(3-pyridyl)borane, 98%

Numéro CAS
89878-14-8
Synonymes
3-(Diethylboryl)pyridine

Dimensions Prix ($) Quantité Disponibilité
5g 31,32
25g 125,10
100g 524,55
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Diethyl(3-pyridyl)borane, 98%

MDL
MFCD00012348

Propriétés chimiques

Formule
C9H14BN
Poids formulaire
147.03
Point de fusion
172-175° lit.
Solubilité
Slightly soluble in water.

Applications

Reactant for: preparation of inhibitors of ataxia telangiectasia mutated and Rad3 related (ATR) protein kinase as potential anticancer agents, N-Methylation reactions of the pyridyl group, Palladium catalyzed amination reactions, intramolecular Heck reactions, Coupling reactions and Synthesis of trisubstituted pyrimidines from polyhalopyrimidines via Suzuki coupling.

Notes

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Références bibliographiques

Minoru Ishikura; Tsukasa Ohta; Masanao Terashima. A Novel Synthesis of 4-Aryl-and 4-Heteroarylpyridines via Diethyl (4-pyridyl) borane. Chemical and Pharmaceutical Bulletin.1985 33(11), 4755-4763.

Antonio Guarna; Ernesto G. Occhiato; Fabrizio Machetti; and Vittoria Giacomellia.19-Nor-10-azasteroids. 5.1 A Synthetic Strategy for the Preparation of (+)-17-(3-Pyridyl)-(5β)-10-azaestra-1,16- dien-3-one, a Novel Potential Inhibitor for Human Cytochrome P45017α (17α-Hydroxylase/C17,20-lyase). J. Org. Chem. 1999 64(13),4985-4989.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
4381494
Code tarifaire harmonisé
2933.39
TSCA
No

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Consulté récemment

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Analytique et matériel de laboratoire