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484-11-7 - 2,9-Dimethyl-1,10-phenanthroline, 98% - Neocuproine - J63698 - Alfa Aesar

J63698 2,9-Dimethyl-1,10-phenanthroline, 98%

Numéro CAS
484-11-7
Synonymes
Neocuproine

Dimensions Prix ($) Quantité Disponibilité
5g 41,20
25g 192,61
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2,9-Dimethyl-1,10-phenanthroline, 98%

MDL
MFCD00004973
EINECS
207-601-9

Propriétés chimiques

Formule
C14H12N2
Poids formulaire
208.26
Forme
Powder
Point de fusion
159-164°
Sensibilité
Light Sensitive
Solubilité
Slightly soluble in water and light petroleum. Soluble in methanol, ethanol, acetone, ether and benzene.

Applications

2,9-Dimethyl-1,10-phenanthroline is used as a reagent for the colorimetric determination of copper and acts as a chelating agent. It is also used in the synthesis of arly ketones.

Notes

Incompatible with strong oxidizing agents.

Références bibliographiques

Ashbrook, L. N.; Elliott, C. M. Dye-Sensitized Solar Cell Studies of a Donor-Appended Bis(2,9-dimethyl-1,10-phenanthroline) Cu(I) Dye Paired with a Cobalt-Based Mediator. J. Phys. Chem. C 2013, 117 (8), 3853-3864.

Xiao, C-L.; Wang, C-Z.; Yuan, L-Y.; Li, B.; He, H.; Wang, S.; Zhao, Y-L.; Chai, Z-F.; Shi, W-Q. Excellent Selectivity for Actinides with a Tetradentate 2,9-Diamide-1,10-Phenanthroline Ligand in Highly Acidic Solution: A Hard-Soft Donor Combined Strategy. Inorg. Chem. 2014, 53 (3), 1712-1720.

Ashbrook, L. N.; Elliott, C. M. Dye-Sensitized Solar Cell Studies of a Donor-Appended Bis(2,9-dimethyl-1,10-phenanthroline) Cu(I) Dye Paired with a Cobalt-Based Mediator. J. Phys. Chem. C. 2013, 117 (8), 3853-3864.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,6449
Code tarifaire harmonisé
2933.99
TSCA
Yes
RTECS
SF8380000

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Catalyseurs

Analytique et matériel de laboratoire