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18912-37-3 - 4-Methoxybenzyl carbazate, 97% - 4-Methoxybenzyl hydrazinocarboxylate - (4-Methoxybenzyl)oxyhydrazine - L00541 - Alfa Aesar

L00541 4-Methoxybenzyl carbazate, 97%

Numéro CAS
18912-37-3
Synonymes
4-Methoxybenzyl hydrazinocarboxylate
(4-Methoxybenzyl)oxyhydrazine

Dimensions Prix ($) Quantité Disponibilité
1g 19,62
5g 76,84
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4-Methoxybenzyl carbazate, 97%

MDL
MFCD00042817
EINECS
242-664-6

Propriétés chimiques

Formule
C9H12N2O3
Poids formulaire
196.21
Point de fusion
75-77°
Solubilité
Insoluble in water.

Applications

It finds its application in the derived azide in N-protection and as a starting material for the azide used to introduce the pMZ-amino protection which is removable under mild hydrolytic conditions.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Références bibliographiques

Jan Legocki, et al. Synthesis and Fungistatic Activity of New Groups of 2,4-Dihydroxythiobenzoyl Derivatives against Phytopathogenic Fungi.J. Agric. Food Chem.,2003,51,(2), 362-368.

Hassan Ali Zamani, et al. Construction of a Highly Selective and Sensitive Ytterbium(III) Membrane Sensor Based on 4-Methoxybenzyl Carbazate as a New Neutral Ionophore.Int. J. Electrochem. Sci.,2013,83429 - 3440.

For use of the derived azide in N-protection, see: Chem. Ber., 95, 1 (1962).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
2052164
Code tarifaire harmonisé
2928.00
TSCA
No

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