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28460-01-7 - Diethyl methylthiomethylphosphonate, 97% - Methylthiomethylphosphonic acid diethyl ester - L00579 - Alfa Aesar

L00579 Diethyl methylthiomethylphosphonate, 97%

Numéro CAS
28460-01-7
Synonymes
Methylthiomethylphosphonic acid diethyl ester

Dimensions Prix ($) Quantité Disponibilité
5g 55,31
25g 195,20
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Diethyl methylthiomethylphosphonate, 97%

MDL
MFCD00015131

Propriétés chimiques

Formule
C6H15O3PS
Poids formulaire
198.22
Point d'ébullition
70-72°/0.2mm
Point d'éclair
101°(213°F)
Densité
1.130
Indice de réfraction
1.4660
Solubilité
It is insoluble in water.

Applications

Diethyl methylthiomethylphosphonate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. Diethyl(methylthiomethyl) phosphonate is a reactant for the synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization. It is used in the preparation of fused nitrogen, sulfur, and phosphorus containing heterocyclic and relevant difurylpyridazine phosphonates with antimicrobial activity. It is also used as a reactant used in the preparation of fused heterocyclic.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Références bibliographiques

EJ Corey.; JI Shulman. Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketones. The Journal of Organic Chemistry. 197035,(3) , 777-780.

J Motoyoshiya.; Y Hongo.; H Tanaka. A Convenient Synthesis of 1, 4-Diketones. Synthetic Communications. . 199121,(8-9) , 997-1000.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319

Causes skin irritation. Causes serious eye irritation.

Mentions de prudence: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Autres références

Beilstein
1705833
Code tarifaire harmonisé
2931.90
TSCA
No

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