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627-27-0 - 3-Buten-1-ol, 98+% - Allyl carbinol - L00767 - Alfa Aesar

L00767 3-Buten-1-ol, 98+%

Numéro CAS
627-27-0
Synonymes
Allyl carbinol

Dimensions Prix ($) Quantité Disponibilité
5g 31,20
25g 110,00
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3-Buten-1-ol, 98+%

MDL
MFCD00002959
EINECS
210-991-3

Propriétés chimiques

Formule
CH2=CHCH2CH2OH
Poids formulaire
72.11
Point d'ébullition
113-114°
Point d'éclair
32°(89°F)
Densité
0.841
Indice de réfraction
1.4210
Solubilité
Soluble in water.

Applications

3-Buten-1-ol is employed in a study of the Mn-catalyzed hydrohydrazination of olefins. Also used in a study of the conversion of propargylic acetates to ethers catalyzed by ferric chloride.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Références bibliographiques

Francisco Caturla.; Carmen Najera. Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol. Tetrahedron. 1997, 53, (33), 11449-11464.

Naoki Yamamoto.; Satoshi Sato.; Ryoji Takahashi.; Kanichiro Inui. Synthesis of 3-buten-1-ol from 1,4-butanediol over ZrO2 catalyst. Journal of Molecular Catalysis A: Chemical. 2006, 243, (1), 52-59.

Can be used to protect enolizable and base-sensitive carboxylic acids as their 3-butenyl esters which can be cleaved by ozonolysis, followed by treatment with DBU or triethylamine: Tetrahedron Lett., 30, 7317 (1989).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
1633504
Classe de danger
3
Groupe d'emballage
III
Code tarifaire harmonisé
2905.29
TSCA
Yes

Recommandé

Consulté récemment

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Catalyseurs

Analytique et matériel de laboratoire