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437-17-2 - Triphenylcarbenium hexafluorophosphate, 98% - Tritylium hexafluorophosphate - Trityl hexafluorophosphate - L03140 - Alfa Aesar

L03140 Triphenylcarbenium hexafluorophosphate, 98%

Numéro CAS
437-17-2
Synonymes
Tritylium hexafluorophosphate
Trityl hexafluorophosphate

Dimensions Prix ($) Quantité Disponibilité
10g 60,87
50g 270,89
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Triphenylcarbenium hexafluorophosphate, 98%

MDL
MFCD00013121
EINECS
207-112-0

Propriétés chimiques

Formule
C19H15F6P
Poids formulaire
388.29
Point de fusion
ca 160° dec.
Sensibilité
Moisture Sensitive
Solubilité
Soluble in water. (27 g/L) at 25°C.

Applications

Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

Notes

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.

Références bibliographiques

Jan Voigt; Thomas Braun. Si-H and Si-Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes.Dalton Transactions.2011, 40 (47), 12699-12704.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.

Autres références

Beilstein
4344297
Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2942.00
TSCA
Yes

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