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352-93-2 - Diethyl sulfide, 96% - Ethyl sulfide - L03493 - Alfa Aesar

L03493 Diethyl sulfide, 96%

Numéro CAS
352-93-2
Synonymes
Ethyl sulfide

Dimensions Prix ($) Quantité Disponibilité
10g 29,56
100g 101,60
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Diethyl sulfide, 96%

MDL
MFCD00009270
EINECS
206-526-9

Propriétés chimiques

Formule
CH3CH2SCH2CH3
Poids formulaire
90.19
Point de fusion
-104°
Point d'ébullition
90-92°
Point d'éclair
-10°(14°F)
Densité
0.835
Indice de réfraction
1.4420
Solubilité
Miscible with alcohol, ethanol and ether. Slightly miscible with carbon tetrachloride. Immiscible with water.

Applications

Diethyl sulfide is used as a solvent for anhydrous mineral salts and in plating baths for coating metals with gold or silver. It is used as a flavoring agent. It is also used in the addition reaction with platinum dichloride to prepare platinum ethynyl dimers and polymers with pendant ferrocenyl group. Further, it is used in the preparation of triethylsulfoniuim ethylsulfate by reaction with sulfuric acid diethyl ester. In addition to this, it is used in the quantification procedure of volatile sulfur compounds by solid-phase microextraction.

Notes

Incompatible with strong oxidizing agents.

Références bibliographiques

Besov, A. S.; Vorontsov, A. V. Adsorption and photocatalytic oxidation of acetone and diethyl sulfide on FeOOH aerosol. Colloid J. 2015, 77 (1), 11-15.

Oksdath-Mansilla, G.; Peñéñory, A. B.; Barnes, I.; Wiesen, P.; Teruel, M. A. Product distribution study of the Cl-atom initiated oxidation of ethyl methyl sulfide and diethyl sulfide. Atmos. Environ. 2014, 85, 41-47.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H315-H319-H335

Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,3854
Beilstein
1696909
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2930.90
TSCA
Yes
RTECS
LC7200000

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Catalyseurs

Analytique et matériel de laboratoire