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96-29-7 - 2-Butanone oxime, 99% - Ethyl methyl ketoxime - Methyl ethyl ketoxime - L08196 - Alfa Aesar

L08196 2-Butanone oxime, 99%

Numéro CAS
96-29-7
Synonymes
Ethyl methyl ketoxime
Methyl ethyl ketoxime

Dimensions Prix ($) Quantité Disponibilité
100ml 19,47
500ml 37,90
1000ml 60,87
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2-Butanone oxime, 99%

MDL
MFCD00013935
EINECS
202-496-6

Propriétés chimiques

Formule
C4H9NO
Poids formulaire
87.12
Point de fusion
-30°
Point d'ébullition
152-153°
Point d'éclair
62°(144°F)
Densité
0.921
Indice de réfraction
1.4430
Solubilité
Soluble in water at 20°C 114 g/L. Soluble in most organic solvents .

Applications

2-Butanone oxime was employed as reagent and solvent in the syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes. It was also used in the synthesis of novel acetaldiimine cobalt complex, [CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]. Methyl ethyl ketoxime is used primarily as an antiskinning agent in alkyd coating resins

Notes

Store away from acids and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away.

Références bibliographiques

Maximilian N Kopylovich, et al. Single-pot template transformations of cyanopyridines on a Pd(II) centre: syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes and their catalytic activity for microwave-assisted Suzuki-Miyaura and Heck reactions. Dalton Trans.,2009,163074-3084.

Hierso J-C, et al. Cobalt-Assisted Condensation of 2-Butanone Oxime and Acetone: Synthesis and X-ray Structure of the Novel Acetaldiimine Complex [CoI2 {((CH3CH2)(CH3) C= NO) 2C (CH3) 2}].Eur. J. Inorg. Chem.,2000,2000(12), 2459-62.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H318-H351-H312-H317-H227

Causes serious eye damage. Suspected of causing cancer. Harmful in contact with skin. May cause an allergic skin reaction. Combustible liquid.

Mentions de prudence: P210-P201-P261-P280-P281-P305+P351+P338-P310-P312-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
1698241
Code tarifaire harmonisé
2928.00
TSCA
Yes
RTECS
EL9275000

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