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78-88-6 - 2,3-Dichloro-1-propene, 98% - L08943 - Alfa Aesar

L08943 2,3-Dichloro-1-propene, 98%

Numéro CAS
78-88-6
Synonymes

Dimensions Prix ($) Quantité Disponibilité
10g 23,40
50g 66,10
250g 244,00
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2,3-Dichloro-1-propene, 98%

MDL
MFCD00000943
EINECS
201-153-8

Propriétés chimiques

Formule
C3H4Cl2
Poids formulaire
110.97
Point de fusion
-83°
Point d'ébullition
93-96°
Point d'éclair
10°(50°F)
Densité
1.209
Indice de réfraction
1.4620
Solubilité
Soluble in water (2g/L).

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

T Neudecker and D Henschler. Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,1986, 107 (1-2), 1-9.

Roland P H Schmitz et. al. Evidence for a radical mechanism of the dechlorination of chlorinated propenes mediated by the tetrachloroethene reductive dehalogenase of Sulfurospirillum muftivorans. Environmental Science & Technology. 2007, 41 (21), 7370-7375.

Reductive elimination with Zn powder gives allene free from methylacetylene: Org. Synth. Coll., 5, 22 (1973).

Electron-acceptor, with concomitant reduction to allene, in a high-yield coupling of aryl Grignard reagents to symmetrical biaryls: Tetrahedron Lett., 29, 1293 (1988):

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H302-H312-H332-H315-H318-H341-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye damage. Suspected of causing genetic defects. May cause respiratory irritation.

Mentions de prudence: P210-P201-P261-P280-P303+P361+P353-P305+P351+P338-P304+P340-P310a-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
1361491
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2903.29
TSCA
Yes
RTECS
UC8400000

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Analytique et matériel de laboratoire