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78-88-6 - 2,3-Dichloro-1-propene, 98% - L08943 - Alfa Aesar

L08943 2,3-Dichloro-1-propene, 98%

Numéro CAS
78-88-6
Synonymes

Dimensions Prix ($) Quantité Disponibilité
10g 21,69
50g 62,36
250g 225,90
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2,3-Dichloro-1-propene, 98%

MDL
MFCD00000943
EINECS
201-153-8

Propriétés chimiques

Formule
C3H4Cl2
Poids formulaire
110.97
Point de fusion
-83°
Point d'ébullition
93-96°
Point d'éclair
10°(50°F)
Densité
1.209
Indice de réfraction
1.4620
Solubilité
Soluble in water (2g/L).

Applications

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

T Neudecker and D Henschler. Mutagenicity of chloroolefins in the Salmonella/mammalian microsome test. III. Metabolic activation of the allylic chloropropenes allyl chloride, 1,3-dichloropropene, 2,3-dichloro-1-propene, 1,2,3-trichloropropene, 1,1,2,3-tetrachloro-2-propene and hexachloropropene by S9 mix via two different metabolic pathways. Mutation Research/Fundamental and Molecular Mechanisms of Mutagenesis,1986, 107 (1-2), 1-9.

Roland P H Schmitz et. al. Evidence for a radical mechanism of the dechlorination of chlorinated propenes mediated by the tetrachloroethene reductive dehalogenase of Sulfurospirillum muftivorans. Environmental Science & Technology. 2007, 41 (21), 7370-7375.

Reductive elimination with Zn powder gives allene free from methylacetylene: Org. Synth. Coll., 5, 22 (1973).

Electron-acceptor, with concomitant reduction to allene, in a high-yield coupling of aryl Grignard reagents to symmetrical biaryls: Tetrahedron Lett., 29, 1293 (1988):

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H318-H315-H341-H302-H312-H332-H335-H412

Highly flammable liquid and vapour. Causes serious eye damage. Causes skin irritation. Suspected of causing genetic defects. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. May cause respiratory irritation. Harmful to aquatic life with long lasting effects.

Mentions de prudence: P210-P201-P261-P273-P280-P281-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
1361491
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2903.29
TSCA
Yes
RTECS
UC8400000

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Analytique et matériel de laboratoire