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814-68-6 - Acryloyl chloride, 96%, stab. with 400ppm phenothiazine - Propenoyl chloride - L10363 - Alfa Aesar

L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

Numéro CAS
814-68-6
Synonymes
Propenoyl chloride

Dimensions Prix ($) Quantité Disponibilité
10g 36,67
50g 57,06
250g 211,15
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Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

MDL
MFCD00000731
EINECS
212-399-0

Propriétés chimiques

Formule
C3H3ClO
Poids formulaire
90.51
Point d'ébullition
74-76°
Point d'éclair
-4°(24°F)
Densité
1.114
Indice de réfraction
1.4350
Sensibilité
Moisture & Light Sensitive
Solubilité
Miscible with water.

Applications

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Notes

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, oxidizing agents, strong bases and polymerizing initiators.

Références bibliographiques

Warneke, J.; Plaumann, M.; Wang, Z.; Böhler, E.; Kemken, D.; Kelm, S.; Leibfritz, D.; Azov, V. A. New insights into the old reaction between acryloyl chlorides and pyridine. Tetrahedron Lett. 2015, 56 (9), 1124-1127.

Lee, P. W.; Scrape, P. G.; Butler, L. G.; Lee, Y. P. Two HCl-Elimination Channels and Two CO-Formation Channels Detected with Time-Resolved Infrared Emission upon Photolysis of Acryloyl Chloride [CH2CHC(O)Cl] at 193 nm. J. Phys. Chem. A 2015, 119 (28), 7293-7304.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H330-H302-H314-H318

Highly flammable liquid and vapour. Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P210-P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
635744
Classe de danger
6.1
Groupe d'emballage
I
Code tarifaire harmonisé
2916.19
TSCA
Yes
RTECS
AT7350000

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Analytique et matériel de laboratoire