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54132-75-1 - 3,5-Dimethylphenyl isocyanate, 97% - L11698 - Alfa Aesar

L11698 3,5-Dimethylphenyl isocyanate, 97%

Numéro CAS
54132-75-1
Synonymes

Dimensions Prix ($) Quantité Disponibilité
1g 23,22
5g 56,80
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3,5-Dimethylphenyl isocyanate, 97%

MDL
MFCD00013868
EINECS
258-987-0

Propriétés chimiques

Formule
C9H9NO
Poids formulaire
147.18
Point d'ébullition
205°
Point d'éclair
83°(181°F)
Densité
1.045
Indice de réfraction
1.5280
Sensibilité
Moisture Sensitive
Solubilité
Hydrolyzes in water.

Applications

3,5-Dimethylphenyl isocyanate is applications include linking with oligosaccharides and cyclodextrins for chiral chromatography stationary phases.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Références bibliographiques

Tihamer Hargitai.; Yoshio Okamoto. Evaluation of 3,5-Dimethylphenyl Carbamoylated α-, β-, and γ-Cyclodextrins as Chiral Stationary Phases for HPLC. Journal of Liquid Chromatography. 1993, 16 (4), 843-858.

Pilar Franco.; Antonio Senso.; Cristina Minguillón.; Laureano Oliveros. 3,5-Dimethylphenylcarbamates of amylose, chitosan and cellulose bonded on silica gel: Comparison of their chiral recognition abilities as high-performance liquid chromatography chiral stationary phases. Journal of Chromatography A. 1998, 796 (2), 265-272.

Reaction with oligosaccharides and cyclodextrins gives 3,5-dimethylcarbamates which have been evaluated as chiral stationary phases for HPLC: J. Chromat., 628, 11 (1993); Bull. Chem. Soc. Jpn., 63, 3606 (1990).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H300-H330-H315-H319-H335-H334-H227

Fatal if swallowed. Fatal if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Combustible liquid.

Mentions de prudence: P210-P260-P284-P301+P310-P304+P340-P305+P351+P338-P320-P330-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
774958
Classe de danger
6.1
Groupe d'emballage
II
Code tarifaire harmonisé
2929.10
TSCA
No

Recommandé

  • A16298

    3,4-Dichlorophenyl isocyanate, 97%
  • L10470

    4-Chloro-2-methylphenyl isocyanate, 98%
  • L11567

    5-Chloro-2-methylphenyl isocyanate, 98%
  • L12016

    4-Chloro-3-(trifluoromethyl)phenyl isocyanate, 97%
  • L14780

    2,3-Dichlorophenyl isocyanate, 97%

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