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131307-35-2 - N-Fluoropyridinium pyridine heptafluorodiborate, 90+% - AccuFluor NFPy - L13231 - Alfa Aesar

L13231 N-Fluoropyridinium pyridine heptafluorodiborate, 90+%

Numéro CAS
131307-35-2
Synonymes
AccuFluor NFPy

Dimensions Prix ($) Quantité Disponibilité
1g 50,40
5g 190,00
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N-Fluoropyridinium pyridine heptafluorodiborate, 90+%

MDL
MFCD00142628

Propriétés chimiques

Formule
C10H10B2F8N2
Poids formulaire
331.81
Point de fusion
196-200°
Solubilité
Water and organic soluble.

Applications

N-Fluoropyridinium pyridine heptafluorodiborate, is used as moderately powerful electrophilic fluorinating agent, especially for transfer of fluorine to reactive sites of activated olefins (enol esters, silyl enol ethers, enamines) and sulfides. The reactions can be carried out in conventional glass equipment in a solvent such as acetonitrile.

Notes

Stable, non-hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents, bases. Stable under recommended storage conditions.

Références bibliographiques

AJ Poss.; M Van Der Puy.; D Nalewajek. N-Fluoropyridinium pyridine heptafluorodiborate: A useful fluorinating agent. J. Org. Chem. 1991, 56,(20), 5962-5964.

AccuFluor is a registered trademark of AlliedSignal Inc.

Stable, non-hygroscopic, water- and organic-soluble, moderately powerful electrophilic fluorinating agent, especially for transfer of fluorine to reactive sites of activated olefins (enol esters, silyl enol ethers, enamines) and sulfides. The reactions can be carried out in conventional glass equipment in a solvent such as acetonitrile: J. Org. Chem., 56, 5962 (1991).

Technical brochure available on request.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2933.39
TSCA
No

Recommandé

  • L14324

    N-Fluoropyridinium trifluoromethanesulfonate, 95%
  • 89541

    Chloroform-d, 99.8% (Isotopic)

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Analytique et matériel de laboratoire