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1313-13-9 - Manganese(IV) oxide activated, tech. 90% - Manganese dioxide - L13253 - Alfa Aesar

L13253 Manganese(IV) oxide activated, tech. 90%

Numéro CAS
Manganese dioxide

Dimensions Prix ($) Quantité Disponibilité
10g 19,00
100g 22,30
500g 81,80
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Manganese(IV) oxide activated, tech. 90%


Propriétés chimiques

Poids formulaire
Point de fusion
ca 535° dec.
Insoluble in water.


Manganese(IV) oxide is suitable for use in batteries. It is widely used for the selective oxidation of allylic and benzylic alcohols to aldehydes or ketones, as a co-oxidant in combination with 1,4-benzoquinone and in the allylic oxidation of olefins catalyzed by Palladium(II)­ acetate. It acts a reagent for oxidations. It is the source of manganese and all its compounds, largely used in manufacturing of manganese steel, for making amethyst glass, decolorizing glass, painting on porcelain, faience and majolica. The precipitate is used in electrotechnics, pigments, browning gun barrels, drier for paints and varnishes, printing and dyeing textiles.


Store at room temperature. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Références bibliographiques

Jay A. Young. Manganese(IV) Oxide. J. Chem. Educ. 2001, 78 (10), 1327.

Jose Alberto Cerri.; Edson Roberto Leite.; Douglas Gouvêa.; Elson Longo.; Jose Arana Varela. Effect of Cobalt(II) Oxide and Manganese(IV) Oxide on Sintering of Tin(IV) Oxide. Journal of the American Ceramic Society. 1996, 79 (3), 799-804.

Mild oxidizing agent. For reviews, see: Synthesis, 65, 133 (1976); J. Prakt. Chem./ Chem. Ztg., 337, 75 (1995). See also M. Hudlicky, Oxidations in Organic Chemistry, ACS Monograph 186, Washington DC (1990).

Widely used for the selective oxidation of allylic and benzylic alcohols to aldehydes or ketones. See, e.g.: Org. Synth. Coll., 7, 102 (1990); 9, 136 (1998).

For use as a co-oxidant, in combination with 1,4-benzoquinone, in the allylic oxidation of olefins, catalyzed by Palladium(II)­ acetate, 10516, see: Org. Synth. Coll., 8, 5, 137 (1993).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H302-H332

Harmful if swallowed. Harmful if inhaled.

Mentions de prudence: P261-P264-P270-P271-P304+P340-P301+P312a-P330-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé


Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux


Analytique et matériel de laboratoire