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87199-15-3 - 3-(Hydroxymethyl)benzeneboronic acid, 98% - 3-(Hydroxymethyl)phenylboronic acid - L15193 - Alfa Aesar

L15193 3-(Hydroxymethyl)benzeneboronic acid, 98%

Numéro CAS
87199-15-3
Synonymes
3-(Hydroxymethyl)phenylboronic acid

Dimensions Prix ($) Quantité Disponibilité
1g 44,20
5g 117,00
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3-(Hydroxymethyl)benzeneboronic acid, 98%

MDL
MFCD01317846

Propriétés chimiques

Formule
C7H9BO3
Poids formulaire
151.96
Point de fusion
93-98°
Solubilité
Soluble in water.

Applications

Reactant used for copper-mediated trifluoromethylation, copper-catalyzed transformations from arylboronic acids in water, Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylate. Reactant involved in the synthesis of biologically active molecules including Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions, HIV protease inhibitors with antiviral activity against drug-resistant viruses, Pyrrole derivatives for use as PDE4B inhibitors.

Notes

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

Cheng-Pan Zhang et. al. Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts.. ChemicalCommunications.2011, 47,(33), 9516-9518.

Haijun Yang et. al. General copper-catalyzed transformations of functional groups from arylboronic acids in water. Chemistry: A European Journal.2011, 17, (20), 5652-5660.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
8832019
Code tarifaire harmonisé
2931.90
TSCA
No

Recommandé

  • 41464

    Toluene, anhydrous, 99.8%
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    Pyridine-4-boronic acid hydrochloride, 95%

Consulté récemment

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Catalyseurs

Analytique et matériel de laboratoire