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55289-06-0 - 3-Methoxy-2-methylbenzoic acid, 97% - 3-Methoxy-o-toluic acid - 2-Methyl-m-anisic acid - L18729 - Alfa Aesar

L18729 3-Methoxy-2-methylbenzoic acid, 97%

Numéro CAS
55289-06-0
Synonymes
3-Methoxy-o-toluic acid
2-Methyl-m-anisic acid

Dimensions Prix ($) Quantité Disponibilité
10g 46,14
50g 116,00
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3-Methoxy-2-methylbenzoic acid, 97%

MDL
MFCD02094039

Propriétés chimiques

Formule
C9H10O3
Poids formulaire
166.18
Solubilité
Soluble in methanol. Insoluble in water.

Applications

3-Methoxy-2-methylbenzoic acid is used as a Corey-Bakshi-Shibata oxazaborolidine catalyst for asymmetric reduction and asymmetric synthesis. It is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols and propargyl alcohols. It is also used in desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents.

Références bibliographiques

Thi-Huu Nguyen.; Nguyet Trang Thanh Chau.; Anne-Sophie Castanet.; Kim Phi Phung Nguyen.; Jacques Mortier. Toward a Better Understanding on the Mechanism of Ortholithiation. Tuning of Selectivities in the Metalation of meta-Anisic Acid by an Appropriate Choice of Base. J. Org. Chem. 2005, 7 (12), 2445-2448.

Yoshiaki Nakagawaa, , , Kazunari Hattoria, Chieka Minakuchia, Soichi Kugimiyaa, Tamio Ueno. Relationships between structure and molting hormonal activity of tebufenozide, methoxyfenozide, and their analogs in cultured integument system of Chilo suppressalis Walker. Steroids. 2000, 65 (3), 117-123.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
510395
Code tarifaire harmonisé
2918.99
TSCA
No

Recommandé

  • H50227

    3-Ethoxybenzoyl chloride, 98%
  • L07337

    1,4-Cyclohexadiene, 97% stab. with 0.1% BHT

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire