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2627-86-3 - (S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5% - L-(-)-alpha-Methylbenzylamine - L19118 - Alfa Aesar

L19118 (S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%

Numéro CAS
2627-86-3
Synonymes
L-(-)-alpha-Methylbenzylamine

Dimensions Prix ($) Quantité Disponibilité
5g 21,69
25g 46,53
100g 121,50
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(S)-(-)-1-Phenylethylamine, ChiPros 99+%, ee 99.5%

MDL
MFCD00064406
EINECS
220-098-0

Propriétés chimiques

Formule
C8H11N
Poids formulaire
121.18
Point de fusion
-10°
Point d'ébullition
187°
Point d'éclair
71°(159°F)
Densité
0.948
Indice de réfraction
1.5260
Sensibilité
Air Sensitive
Solubilité
Slightly miscible with water.

Applications

(S)-(-)-1-Phenylethylamine is utilized in a one-pot, multi-component synthesis of a highly substituted, chiral pyrrole.

Notes

Keep away from sources of ignition. Incompatible with acids, acid chlorides, acid anhydrides and strong oxidizing agents.

Références bibliographiques

For use as a chiral auxiliary in the asymmetric synthesis of (R)-(-)-10-methyl-1(9)-octal-2-one, see: Org. Synth. Coll., 9, 610 (1998):

Cassimjee, K. E.; Humble, M. S.; Land, H.; Abedi, V.; Berglund, P. Chromobacterium violaceum ω-transaminase variant Trp60Cys shows increased specificity for (S)-1-phenylethylamine and 4'-substituted acetophenones, and follows Swain-Lupton parameterisation. Org. Biomol. Chem. 2012, 10 (28), 5466-5470.

Cui, S.; Wang, T.; Hu, X. Synthesis, characterization, and DFT studies of a new chiral ionic liquid from (S)-1-phenylethylamine. Spectrochim. Acta, Part A 2014, 133, 778-784.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H311-H302-H314-H318-H227

Toxic in contact with skin. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Mentions de prudence: P210-P260-P280-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,6026
Beilstein
2204907
Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2921.49
TSCA
Yes

Recommandé

  • A10632

    Ammonium thiocyanate, 98+%
  • A14320

    N-Iodosuccinimide, 97%
  • L19117

    (R)-(+)-1-Phenylethylamine, ChiPros 99+%, ee 99+%
  • L19299

    (S)-(-)-N-Benzyl-1-phenylethylamine, ChiPros 99%, ee 99+%
  • 33337

    Magnesium sulfate, anhydrous, 99.5% min

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire