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12107-56-1 - Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7% - 10493 - Alfa Aesar

10493 Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

Codice CAS
12107-56-1
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 76,58
5g 256,08
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Dichloro(1,5-cyclooctadiene)palladium(II), Pd 36.7%

MDL
MFCD00012412
EINECS
235-161-8

Proprietà chimiche

Formula
C8H12Cl2Pd
Peso formula
285.49
Modulo
Crystalline
Sensibilità
Hygroscopic
Solubilità
Soluble in dichloromethane

Applicazioni

Dichloro(1,5-cyclooctadiene)palladium(II) is used as catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes, Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate and methoxycarbonylation of iodobenzene.

Note

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. It is sensitive to air. It is hygroscopic in nature. Incompatible with oxidizing agents.

Letteratura

J.K. Stille.; D.E. James. The palladium(II)catalyzed olefin carbonylation reactions. The stereochemistry of the hydroxypalladation of cyclooctadiene . Journal of Organometallic Chemistry. 1976, 108 (3), 401-408.

Horst Kunkely, Arnd Vogler. Electronic spectrum and photoreactivity of dichloro(1,5-cyclooctadiene)-palladium(II). Journal of Organometallic Chemistry. 1998, 559 (1-2), 223-225.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2843.90
TSCA
Yes

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