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15020-99-2 - Dichloro(ethylenediamine)palladium(II), Pd 44.8% - 10496 - Alfa Aesar

10496 Dichloro(ethylenediamine)palladium(II), Pd 44.8%

Codice CAS
15020-99-2
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 113,00
5g 484,00
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Dichloro(ethylenediamine)palladium(II), Pd 44.8%

MDL
MFCD00044991

Proprietà chimiche

Formula
PdCl2(H2NCH2CH2NH2)
Peso formula
237.41
Modulo
Crystalline
Sensibilità
Hygroscopic
Solubilità
Very low solubility in water.

Applicazioni

Catalyst for C-C coupling reactions like Sonogashira coupling. Formation of host-guest complexes. Synthesis of mixed-metal, mixed-pyrimidine self-assembling metallacalix[n]arenes; ring-in-ring complex; binding of metal with glycose phosphates.

Note

Stable. Hygroscopic. Not compatible with strong oxidizing agents.

Letteratura

Bakherad, M.; Bahramian, B.; Nasr-Isfahani, H.; Ali Keivanloo, A.; Doostmohammadi, N. Polystyrene-supported Palladium(II) Ethylenediamine Complex: A highly Active and Recyclable Catalyst for the Synthesis of 2-Benzylimidazo[2,1-b]pyridines through Heteroannulation of acetylenic Compounds. J. Heterocycl. Chem. 2009, 46 (1), 100-104.

Bardají, E. G.; Freisinger, E.; Costisella, B.; Schalley, C. A.; Brüning, W.; Sabat, M.; Lippert, B. Mixed-Metal (Platinum, Palladium), Mixed-Pyrimidine (Uracil, Cytosine) Self-Assembling Metallacalix[n]arenes: Dynamic Combinatorial Chemistry with Nucleobases and Metal Species. Chem. Eur. J. 2007, 13 (21), 6019-6039.

Bach, S. B. H.; Green, C. E.; Nagore, L. I.; Sepeda, T. G.; Merrill, G. N. Complexes of dichloro(ethylenediamine)palladium(II) observed from aqueous solutions by electrospray mass spectrometry. J. Am. Soc. Mass Spectrom. 2007, 18 (4), 769-777.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Codice tariffe armonizzato
2843.90
TSCA
No

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