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10361-44-1 - Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10657 - Alfa Aesar

10657 Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

Codice CAS
10361-44-1
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
25g 77,90
100g 232,00
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Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00003460
EINECS
233-791-8

Proprietà chimiche

Formula
Bi(NO3)3•xH2O
Peso formula
394.99(anhy)
Modulo
Crystalline
Punto di fusione
30° dec.
Sensibilità
Hygroscopic
Solubilità
Slightly soluble in water; soluble in acetone, acetic acid, and glycerol. Insoluble in ethyl acetate and ethanol.

Applicazioni

It is used in electronic ceramics and fluorescent paints. It is employed as an oxidant for selective oxidation of sulfides to sulfoxides, as a nitrating reagent for synthesizing nitro aromatic compounds, and as a precursor for Dragendorff reagent for use in TLC stain and for testing the presence of alkaloids. On silica gel support, it has been reported to be an efficient catalyst for the Biginelli reaction.

Note

Hygroscopic. Stable. On heating it decomposes to form nitrogen dioxide. Incompatible with strong acids, strong reducing agents, organic materials, and finely powdered metals.

Letteratura

Polanki, I. K.; Kurma, S. H.; Bhattacharya, A. K. Direct Glycosylation of Unprotected and Unactivated Sugars Using Bismuth Nitrate Pentahydrate. J. Carbohydr. Chem. 2015, 34 (4), 196-205.

Miersch, L.; Schlesinger, M.; Troff, R. W.; Schalley, C. A.; Rüffer, T.; Heinrich Lang, H.; Zahn, D.; Mehring, M. Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters. Chem-Eur. J. 2011, 17 (25), 6985-6990.

Park, Y.; McDonald, K. J.; Choi, K. Progress in Bismuth Vanadate Photoanodes for Use in Solar Water Oxidation. Chem. Soc. Rev. 2013, 42, 2321-2337.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P221-P210v-P220-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat Keep/Store away from clothing/combustible materials. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,1271
Classe di rischio
5.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2834.29
TSCA
Yes

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