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13778-31-9 - Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10699 - Alfa Aesar

10699 Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

Codice CAS
13778-31-9
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 20,62
25g 60,81
100g 186,43
500g 493,20
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Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149669
EINECS
221-838-5

Proprietà chimiche

Formula
CuN2O6•xH2O
Peso formula
187.55(anhy)
Modulo
Crystalline Aggregates
Sensibilità
Hygroscopic
Solubilità
Soluble in ethanol and water. Insoluble in ethyl acetate.

Applicazioni

It serves as a catalyst for oxidative coupling of 2,6-dimethylphenol, resulting in an important engineering polymer material. Also used in textiles and polishing agents for other metals. It is a precursor for copper oxide, which finds use as a catalyst for many organic transformations. Menke conditions employ copper nitrate for aromatic nitrations. Claycop reagent, the hydrated copper nitrate deposited on clay, finds use in many organic reactions, for example, oxidation of dithioacetals to carbonyls and thiols to disulfides.

Note

Hygroscopic. On heating, it forms basic copper nitrate containing hydroxy anions, and on further heating, it forms cupric oxide liberating nitrogen dioxide and oxygen.

Letteratura

Gascon, J.; Aguado, S.; Kapteijn, F. Manufacture of Dense Coatings of Cu3(BTC)2 (HKUST-1) on alpha-Alumina. Micropor. Mesopor. Mat. 2008, 113 (1-3), 132-138.

El-Shall, M. S.; Abdelsayed, V.; Khder, A. E. R. S.; Hassan, H. M. A.; El-Kaderi, H. M.; Reich, T. E. Metallic and Bimetallic Nanocatalysts Incorporated into Highly Porous Coordination Polymer MIL-101. J. Mater. Chem. 2009, 19, 7625-7631.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H272-H314-H318-H302

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Dichiarazioni precauzionali: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,2643
Classe di rischio
5.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2834.29
TSCA
Yes
RTECS
GL7875000

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