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14996-61-3 - Iridium(III) chloride hydrate, 99.8% (metals basis) - 11030 - Alfa Aesar

11030 Iridium(III) chloride hydrate, 99.8% (metals basis)

Codice CAS
14996-61-3
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 98,70
5g 368,00
25g 1670,00
50g Prezzo su richiesta. Selezionare “Aggiungere al preventivo” specificando il tipo di confezione.
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Iridium(III) chloride hydrate, 99.8% (metals basis)

MDL
MFCD00149750
EINECS
233-044-6

Proprietà chimiche

Formula
IrCl3•xH2O
Peso formula
298.56(anhy)
Modulo
Crystalline
Solubilità
Soluble in water and alcohol.

Applicazioni

Iridium(III) chloride hydrate is used to prepare other iridium compounds. It finds use as a catalyst for oxidation in presence of cerium(IV) and in the the manufacture of electrodes. Iridium(III) chloride is used in iridium electroplating, in making the standard meter bar of Paris and crucibles. It is used for high temperature electrical contacts, as hardening agent, in tipping pens and compass bearings and Pt/Ir spark plugs. It is used for medical, surgical or other patient oriented applications, MMO (mixed metal oxide) titanium electrode coatings and as a starting material for heterogeneous catalysts.

Note

Hygroscopic and Incompatible with strong oxidants.

Letteratura

Botelho, M. B. S.; Hernandez, J. M. F.; Queiroz, T. B.; Eckert, H.; Cola, L.; Camargo, A. S. S. Iridium(iii)-surfactant complex immobilized in mesoporous silica via templated synthesis: a new route to optical materials. J. Mater. Chem. 2011, 21, 8829-8834.

Tandon, P. K. ; Sahgal, S.; Srivastava, M.; Singh, S. B. Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2. Appl. Organomet. Chem. 2007, 21 (3), 135-138.

Tandon, P. K.; Sahgal, S.; Gayatri; Purwar, M.; Dhusia, M. Oxidation of Ketones by Cerium(IV) in Presence of Iridium(III) Chloride. J. Mol. Catal. A: Chem. 2006, 250 (1-2), 203-209.

Tandon, P. K.; Singh, A. K.; Sahgal, S.; Kumar, S. Oxidation of Cyclic Alcohols by Cerium(IV) in Acidic Medium in the Presence of Iridium(III) chloride. J. Mol. Catal. A: Chem. 2008, 282 (1-2), 136-143.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,5088
Classe di rischio
8
Gruppo di imballaggio
II
Codice tariffe armonizzato
2843.90
TSCA
Yes

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    Rhodium(III) chloride hydrate, Rh 38.5-45.5%
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min
  • 11051

    Dihydrogen hexachloroplatinate(IV) hydrate, 99.9% (metals basis)

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