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7647-10-1 - Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min - 11034 - Alfa Aesar

11034 Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min

Codice CAS
7647-10-1
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
0.5g 33,20
2g 102,00
10g 450,00
50g 2047,00
100g Prezzo su richiesta. Selezionare “Aggiungere al preventivo” specificando il tipo di confezione.
250g Prezzo su richiesta. Selezionare “Aggiungere al preventivo” specificando il tipo di confezione.
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Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min

MDL
MFCD00003558
EINECS
231-596-2

Proprietà chimiche

Formula
PdCl2
Peso formula
177.31
Modulo
Crystalline
Punto di fusione
675° dec.
Densità
4.0
Solubilità
Soluble in dilute mineral acids, aqueous metal halides.Soluble in cold water, organic solvents and hydrochloric acid.

Applicazioni

Catalyst precursor.Palladium(II) chloride is used to remove the stain present in stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tattooing of leukomas in the cornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.

Note

Moisture sensitive. Incompatible with organic solvents, acids, ammonia, zinc, strong oxidizing agents, aluminum, magnesium, nitrates and thiocyanates.

Letteratura

Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.

Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.

Janreddy, D.; Kavala, V.; Kotipalli, T.; Kuo, C.; Kuo, T.; Chen, M.; He, T.; Yao, C. Palladium(II) Chloride-Catalyzed Aerobic Oxidative Intermolecular Cycloaddition Reaction of 2-Alkynylbenz- aldehydes and Electron-Deficient Terminal Alkenes: An Efficient Synthesis of Naphthyl Ketones. Adv. Synth. Catal. 2014, 356 (14-15), 3083-3091.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H290-H303-H318-H317

May be corrosive to metals. May be harmful if swallowed. Causes serious eye damage. May cause an allergic skin reaction.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P310a-P406-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store in corrosive resistant container with a resistant inner liner. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,6990
Codice tariffe armonizzato
2843.90
TSCA
Yes
RTECS
RT3500000

Raccomandato

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  • 11487

    Iron(III) fluoride, anhydrous, 97% min
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    Tin(II) chloride, anhydrous, 99% min

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