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10025-99-7 - Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min - 11048 - Alfa Aesar

11048 Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min

Codice CAS
10025-99-7
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 116,00
5g 520,00
25g Pricing available on request. Click Add to Quote Request button and specify size.
50g Pricing available on request. Click Add to Quote Request button and specify size.
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Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min

MDL
MFCD00011378
EINECS
233-050-9

Proprietà chimiche

Formula
Cl4K2Pt
Peso formula
415.11
Modulo
Crystalline
Punto di fusione
dec.
Densità
3.38
Solubilità
Soluble in hot water. Slightly soluble in water.

Applicazioni

Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.

Note

Incompatible with strong oxidizing agents and acids.

Letteratura

Wang, H.; Imura, M.; Malgras, V.; Li, C.; Wang, L.; Yamauchi, Y. A Solution Phase Synthesis of Dendritic Platinum Nanoelectrocatalysts with the Assistance of Polyoxyethylene Nonylphenyl Ether. J. Inorg. Organomet. Polym. Mater. 2015, 25 (2), 245-250.

Kozhevnikov, V. N.; Donnio, B.; Heinrich, B.; Williams, J. G.; Bruce, D. W. Green-blue light-emitting platinum(II) complexes of cyclometallated 4, 6-difluoro-1, 3-dipyridylbenzenes showing mesophase organisation. J. Mater. Chem. C 2015, 3 (39), 10177-10187.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H301-H315-H317-H334-H318-H290

Toxic if swallowed. Causes skin irritation. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes serious eye damage. May be corrosive to metals.

Dichiarazioni precauzionali: P285-P261-P280-P301+P310-P305+P351+P338-P310-P342+P311-P362-P405-P501a

In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,7682
Classe di rischio
6.1
Gruppo di imballaggio
III
Codice tariffe armonizzato
2843.90
TSCA
Yes
RTECS
TP1850000

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