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563-63-3 - Silver acetate, anhydrous, 99% - 11660 - Alfa Aesar

11660 Silver acetate, anhydrous, 99%

Codice CAS
563-63-3
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
25g 86,73
100g 277,07
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Silver acetate, anhydrous, 99%

MDL
MFCD00012446
EINECS
209-254-9

Proprietà chimiche

Formula
C2H3AgO2
Peso formula
166.92
Modulo
Crystalline
Punto di fusione
dec.
Densità
3.26
Sensibilità
Light Sensitive
Solubilità
Soluble in dilute HNO{3}. Solubility in water increases with temperature.

Applicazioni

It finds use in gum, spray, and lozenges to prevent smokers from smoking. When mixed with smoke, silver acetate creates an unpleasant metallic taste in the smoker's mouth, thus prevent them from smoking. It is a reagent in the laboratory as a source of silver ions lacking an oxidizing anion. It is a reagent for direct ortho-arylation, and for conversion of organohalogen compounds into alcohols. Woodward cis-hydroxylation reaction employs silver acetate and iodine for selective conversin of alkenes into cis-diols. Silver acetate is the more preferred reagent for facile carbonylation of primary and secondary amines. It is also employed in the preparation of highly reflective, conductive silvered polymer films.

Note

It is a crystalline solid; photosensitive in nature.

Letteratura

Abbiati, F.; Rossi, E. Silver and Gold Catalyzed Multicomponent Reactions. Beilstein J. Org. Chem. 2014, 10, 481-513.

Jeanmonod, P.; Laschke, M. W.; Gola, N.; von Heesen, M.; Glanemann, M.; Dold, S.; Menger, M. D.; Moussavian, M. R. Silver Acetate Coating Promotes Early Vascularization of Dacron Vascular Grafts without Inducing Host Tissue Inflammation. J. Vasc. Surg. 2013, 58 (6), 1637-1643.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H400-H410-H315

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Causes skin irritation.

Dichiarazioni precauzionali: P273-P280-P264-P362-P321-P332+P313-P302+P352-P391-P501a

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. Collect spillage. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,8505
Classe di rischio
9
Gruppo di imballaggio
III
Codice tariffe armonizzato
2843.29
TSCA
Yes
RTECS
AJ4100000

Raccomandato

  • 11414

    Silver nitrate, ACS, 99.9+% (metals basis)
  • 11420

    Silver carbonate, 99.5% (metals basis)
  • 36200

    Titanium(IV) oxide, anatase, 99.6% (metals basis)
  • 36504

    Formic acid, ACS, 88+%
  • 39742

    Gold(III) acetate, 99.9% (metals basis)

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