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11832 Molybdenum(V) chloride, 99.6% (metals basis)

Codice CAS
10241-05-1
Sinonimi

Stock No. Dimensioni Prezzo ($) Quantità Disponibilità
11832-06 5g 31,90
11832-18 50g 93,30
11832-30 250g 402,00
11832-A1 1kg 1471,00
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Molybdenum(V) chloride, 99.6% (metals basis)

MDL
MFCD00003467
EINECS
233-575-3

Proprietà chimiche

Formula
MoCl5
Peso formula
273.24
Modulo
Crystalline
Punto di fusione
194°
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubilità
Soluble in dry ether, dry alcohol, organic solvents and chlorinated solvents.

Applicazioni

Molybdenum pentachloride is employed as a brazing and soldering flux for monel, tungsten alloys and copper. It has been proven to be an efficient catalyst for the chlorination of aromatic rings and oxidative coupling reactions. It is a strong oxidizing agent. In the Friedel-Craft reaction, molybdenum pentachloride is used as a good lewis acid. Molybdenum pentachloride is used to prepare molybdenum by vapor deposition method.

Note

It is hygroscopic and very sensitive to moisture, oxygen and oxygen-containing compounds.

Letteratura

Cho, H. Y.; Scott, L. T. Oxidative cyclotrimerization of unsaturated compounds with DDQ and triflic acid: An efficient synthetic route to triply-fused benzene rings. Tetrahedron Lett. 2015, 56 (23), 3458-3462.

Freudenmanna, D.; Feldmann, C. The chloridomolybdenum (III) cluster in [BMIm]4[AgMo10Cl35] with infinite chains of Ag+-linked [Mo10Cl35]5- wheels. Dalton Trans. 2014, 43, 14109-14113.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H314-H318-H351

Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of causing cancer.

Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
8
Gruppo di imballaggio
III
Codice tariffe armonizzato
2827.39
TSCA
Yes
RTECS
QA4690000

Raccomandato

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    Trifluoromethanesulfonic anhydride, 98%
  • 12337

    Tungsten(VI) chloride, 99%
  • 14034

    Molybdenum(III) chloride, 99.5% (metals basis)
  • 36691

    Tin granules, ACS, 99.5% min
  • 48117

    Molybdenum(IV) oxide, 99% (metals basis)

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