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534-17-8 - Cesium carbonate, Puratronic®, 99.994% (metals basis) - 12117 - Alfa Aesar

12117 Cesium carbonate, Puratronic®, 99.994% (metals basis)

Codice CAS
534-17-8
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
5g 32,30
25g 110,00
100g 307,00
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Cesium carbonate, Puratronic®, 99.994% (metals basis)

MDL
MFCD00010957
EINECS
208-591-9

Proprietà chimiche

Formula
Cs2CO3
Peso formula
325.82
Modulo
Powder/Granules
Punto di fusione
610° dec.
Densità
4.072
Sensibilità
Hygroscopic
Solubilità
Highly soluble in water. Soluble in alcohol, dimethyl sulfoxide and N,N-dimethylformamide. Insoluble in toluene and p-xylene.

Applicazioni

Cesium carbonate is the precursor for other cesium compounds. It acts as a base in sensitive organic reactions. Suzuki, Heck and Sonogashira synthesis are some of the important reactions involving cesium carbonate. It finds use in solar cells as it increases the power conversion efficiency of cells through the transfer of electrons. It is also used in the production of special optical glasses, petroleum catalytic additives, special ceramics, and in sulfuric acid industry. It is useful in the N-alkylation (of sulfonamides, β-lactams, indoles, heterocycles, and several sensitive nitrogen compounds), carbamination of amines, carbonylation of alcohols, and aerobic oxidation of alcohols into carbonyl compounds without over oxidations.

Note

Hygroscopic. It should not be kept in direct sunlight and at extremely high or low temperature. It should be used in a well ventilated area to prevent the formation of vapours. It is incompatible with strong oxidizing agents, metals and acids.

Letteratura

Chen, Y. C.; Gao, C. Y.; Chen, K. L.; Huang, C. J. Enhanced radiative decay in organic light-emitting diodes by combination of cesium carbonate and silver nanocluster. J. Lumin. 2015, 166, 248-252.

Chen, Y. C.; Gao, C. Y.; Chen, K. L.; Sze, P. W.; Huang. C. J. Enhanced electronic injection in organic light-emitting diodes by incorporating silver nanoclusters and cesium carbonate. J. Lumin. 2015, 351, 232-235.

Granados, M. L.; Poves, M. D. Z.; Alonso, D. M.; Mariscal, R.; Galisteo, F. C.; Moreno-Tost, R.; Santamaría, J.; Fierro, J. L. G. Biodiesel from sunflower oil by using activated calcium oxide. Appl. Catal. B 2007, 73 (3-4), 317-326.

Kondoh, A.; Yorimitsu, H.; Oshima, K. Nucleophilic Aromatic Substitution Reaction of Nitroarenes with Alkyl or Arylthio Groups in Dimethyl Sulfoxide by Means of Cesium carbonate. Tetrahedron 2006, 62 (10), 2357-2360.

Yang, H. B.; Dong, Y. Q.; Wang, X.; Khoo, S. Y.; Liu, B. Cesium Carbonate Functionalized Graphene Quantum Dots as Stable Electron-Selective Layer for Improvement of Inverted Polymer Solar Cells. ACS Appl. Mater. Interfaces 2014, 6 (2), 1092-1099.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H303-H315-H319-H335

May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Merck
14,2010
Beilstein
4546405
Codice tariffe armonizzato
2836.99
TSCA
Yes
RTECS
FK9400000

Raccomandato

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    Lithium carbonate, Puratronic®, 99.998% (metals basis excluding Ca), Ca LT 20ppm
  • 10838

    Potassium carbonate, Puratronic®, 99.997% (metals basis)
  • 10861

    Sodium carbonate, anhydrous, Puratronic®, 99.997% (metals basis)
  • 10897

    Titanium(IV) oxide, Puratronic®, 99.995% (metals basis)
  • 11248

    Neodymium(III) oxide, REacton®, 99.9% (REO)

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