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Cesium carbonate is the precursor for other cesium compounds. It acts as a base in sensitive organic reactions. Suzuki, Heck and Sonogashira synthesis are some of the important reactions involving cesium carbonate. It finds use in solar cells as it increases the power conversion efficiency of cells through the transfer of electrons. It is also used in the production of special optical glasses, petroleum catalytic additives, special ceramics, and in sulfuric acid industry. It is useful in the N-alkylation (of sulfonamides, β-lactams, indoles, heterocycles, and several sensitive nitrogen compounds), carbamination of amines, carbonylation of alcohols, and aerobic oxidation of alcohols into carbonyl compounds without over oxidations.
Chen, Y. C.; Gao, C. Y.; Chen, K. L.; Huang, C. J. Enhanced radiative decay in organic light-emitting diodes by combination of cesium carbonate and silver nanocluster. J. Lumin. 2015, 166, 248-252.
Chen, Y. C.; Gao, C. Y.; Chen, K. L.; Sze, P. W.; Huang. C. J. Enhanced electronic injection in organic light-emitting diodes by incorporating silver nanoclusters and cesium carbonate. J. Lumin. 2015, 351, 232-235.
Granados, M. L.; Poves, M. D. Z.; Alonso, D. M.; Mariscal, R.; Galisteo, F. C.; Moreno-Tost, R.; Santamaría, J.; Fierro, J. L. G. Biodiesel from sunflower oil by using activated calcium oxide. Appl. Catal. B 2007, 73 (3-4), 317-326.
Kondoh, A.; Yorimitsu, H.; Oshima, K. Nucleophilic Aromatic Substitution Reaction of Nitroarenes with Alkyl or Arylthio Groups in Dimethyl Sulfoxide by Means of Cesium carbonate. Tetrahedron 2006, 62 (10), 2357-2360.
Yang, H. B.; Dong, Y. Q.; Wang, X.; Khoo, S. Y.; Liu, B. Cesium Carbonate Functionalized Graphene Quantum Dots as Stable Electron-Selective Layer for Improvement of Inverted Polymer Solar Cells. ACS Appl. Mater. Interfaces 2014, 6 (2), 1092-1099.
Dichiarazioni di rischio (UE): H303-H315-H319-H335
May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Dichiarazioni precauzionali: P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.