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It is used in chemo-therapeutics. It is employed as a catalyst in the removal of tert-butyl(dimethyl)silyl (TBS) protecting groups. It is selective in the presence of aromatic TBS ethers, aliphatic triisopropylsilyl ethers, aliphatic tert-butyl(diphenyl)silyl ethers, or sterically hindered aliphatic TBS ethers. With excess catalyst, TBS ethers can also be transformed into 4-methoxybenzyl ethers or methyl ethers in one pot.
Shi, R. X.; Liu, Y. K.; Xu, Z. Y. Sodium tetrachloroaurate(III) dihydrate-catalyzed efficient synthesis of 1,5-benzodiazepine and quinoxaline derivatives. J. Zhejiang Univ.-SCI. B 2010, 11 (2), 102-108.
Fong, Y. Y.; Visser, B. R.; Gascooke, J. R.; Cowie, B. C. C.; Thomsen, L.; Metha, G. F.; Buntine, M. A.; Harris, H. H. Photoreduction Kinetics of Sodium Tetrachloroaurate under Synchrotron Soft X-ray Exposure. Langmuir 2011, 27 (13), 8099-8104.
Qi, Z.; Xiugin, K.; Lei, L.; Lijuan, Z.; Yonghai, C. Mild and Selective Deprotection of tert-Butyl(dimethyl)silyl Ethers with Catalytic- Amounts of Sodium Tetrachloroaurate(III) Dihydrate. Synthesis 2015, 47 (1), 55-64.
Dichiarazioni di rischio (UE): H290-H302-H314-H318
May be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.
Dichiarazioni precauzionali: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.