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34513-98-9 - Ruthenium(III) nitrosylnitrate, Ru 31.3% min - 12175 - Alfa Aesar

12175 Ruthenium(III) nitrosylnitrate, Ru 31.3% min

Codice CAS
34513-98-9
Sinonimi

Dimensioni Prezzo ($) Quantità Disponibilità
1g 73,20
5g 261,00
25g 1180,00
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Ruthenium(III) nitrosylnitrate, Ru 31.3% min

MDL
MFCD00016313
EINECS
252-068-8

Proprietà chimiche

Formula
N4O10Ru
Peso formula
317.09
Modulo
Crystalline
Punto di fusione
dec.
Solubilità
Miscible with cold water.

Applicazioni

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Note

Incompatible with reducing agents, phosphorus, sulfur and organic matter.

Letteratura

Zoehrer, H.; Mayr, F.; Vogel, F. Stability and Performance of Ruthenium Catalysts Based on Refractory Oxide Supports in Supercritical Water Conditions. Energy Fuels 2013, 27 (8), 4739-4747.

Rose, M. J.; Mascharak, P. K. Photoactive Ruthenium Nitrosyls: Effects of Light and Potential Application as NO Donors. Coord. Chem. Rev. 2008, 252 (18-20), 2093-2114.

Rischio GHS e dichiarazioni precauzionali

Dichiarazioni di rischio (UE): H272-H314-H318-H290

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals.

Dichiarazioni precauzionali: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Altri riferimenti

Classe di rischio
5.1
Gruppo di imballaggio
II
Codice tariffe armonizzato
2843.90
TSCA
Yes

Raccomandato

  • 10561

    Rhodium(III) 2,4-pentanedionate, Premion®, 99.99% (metals basis), Rh 25.2% min
  • 10694

    Cobalt(II) nitrate hexahydrate, Puratronic®, 99.999% (metals basis)
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min
  • 11329

    Cerium(III) nitrate hexahydrate, REacton®, 99.5% (REO)
  • 11341

    Cobalt(II) nitrate hexahydrate, 97.7% min

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